Imagine a single garment that could adapt to changing weather conditions, keeping its wearer cool in the heat of midday but warm when an evening storm blows in. In addition to wearing it outdoors, such clothing could also be worn indoors, drastically reducing the need for air conditioning or heat. Now, researchers reporting in ACS Applied Materials & Interfaces have made a strong, comfortable fabric that heats and cools skin, with no energy input.
 

The researchers freeze-spun silk and chitosan, a material from the hard outer skeleton of shellfish, into colored fibers with porous microstructures. They filled the pores with polyethylene glycol (PEG), a phase-changing polymer that absorbs and releases thermal energy. Then, they coated the threads with polydimethylsiloxane to keep the liquid PEG from leaking out. The resulting fibers were strong, flexible and water-repellent. To test the fibers, the researchers wove them into a patch of fabric that they put into a polyester glove. When a person wearing the glove placed their hand in a hot chamber (122 F), the solid PEG absorbed heat from the environment, melting into a liquid and cooling the skin under the patch. Then, when the gloved hand moved to a cold (50 F) chamber, the PEG solidified, releasing heat and warming the skin. The process for making the fabric is compatible with the existing textile industry and could be scaled up for mass production, the researchers say.